Water

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11th Chemistry NCERT notes

Human body has about 65% and some plants have nearly 95% water.

Water is the most abundant and widely distributed on the earth. it occurs in all the three physical states. H2o is a covalent molecule in which oxygen is sp3 hybridised. It has bent structure.

Structure of water
Structure of water

Physical properties of water:

  • Freezing point of water is 273.15 K and boiling point 373.15 K.
  • Maximum density of water at 4oC is 1 gm cm-3.
  • It is a colourless and tasteless liquid.
  • Due to hydrogen bonding with polar molecules, even covalent compounds like alcohol and carbohydrates dissolve in water.

Structure of Ice

Structure of Ice

Chemical Properties of Water

Amphoteric nature:

It behaves like an amphoteric substance because it can act as an acid as well as base.

Amphoteric nature of water

Autoprotolysis of water also accounts for its amphoteric nature according to Bronsted-Lowry concept.

Amphoteric nature of water

pH of water is 7. And it is neutral towards pH.

Oxidising and Reducing Nature:

Water can act as an oxidising as well as reducing agent.

As an oxidising agent:

Oxidising and Reducing Nature

As reducing agent:

Oxidising and Reducing Nature

Hydrolysis Reaction:

It has a very strong hydrating tendency. It can hydrolyse a large number of compounds such as oxides, halides, carbides etc.

Hydrolysis Reaction

Hydrates Formation:

From aqueous solutions many salts can be crystallised as hydrated salts. Hydrates are of three types:

Coordinated water:

For example:

Hydrates Formation

  • Interstitial water

For example: BaCl2. 2H2O

  • Hydrogen bonded water

For example:

Hydrates Formation

Hard and Soft Water

Hard water

Water which does not produce lather with soap easily is called hard water. Presence of calcium and magnesium salts in the form of hydrogen carbonate, chloride and sulphate in water makes the water hard.

Types of Hardness of Water

Temporary Hardness:

It is due to the presence of bicarbonates of calcium and magnesium in water.

Removal of temporary Hardness

It can be achieved:

  1. By boiling: The soluble bicarbonates are converted into insoluble carbonates.
  2. By Clark’s process: By adding lime water or milk of lime.

Permanent Hardness:

It is due to the presence of chlorides and sulphates of calcium and magnesium.

Removal of Permanent Hardness

  • By adding washing soda: The calcium or magnesium salts are precipitated as carbonates.

Removal of Permanent Hardness by adding washing soda

  • By adding caustic soda: The temporary and permanent hardness can be removed by adding caustic soda.

Removal of Permanent Hardness by adding caustic sda

  • Calgon’s process: Calgon is sodium hexa metaphosphate (Na6P6O18). This calgone when added to hard water form soluble complex.

Removal of Permanent Hardness bt Calgon's process

Similarly, Mg2+ can also precipitate as Na2[Mg2(PO3)6] and water becomes free from Ca2+ and Mg2+ Ions.

  • Permutit process: Permutit is hydrated sodium aluminium silicate Na2Al2Si2O8.xH2O. It exchanges its sodium ions for divalent ions Ca2+ and Mg2+.

Removal of Permanent Hardness by Permutit process

Permutit when fully exhausted can be regenerated by treating with 10% solution of sodium chloride. It is most efficient method to gel water with zero degree of hardness.

  • By synthetic resins:
  • Cation exchange resins
  • Anion exchange resins

Soft Water

Water which readily forms lather with soap is called soft water.

For example: Rainwater, distilled water

 

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